BQQDB - SULFURIC ACID, A-300
- MSDS: BQQDB
- Manufacturer: E C APPARATUS CORP
- Product Name: SULFURIC ACID, A-300
- National Stock Number: 6810-00-146-7515
Product Identification
Product ID:SULFURIC ACID, A-300
MSDS Date:09/15/1988
FSC:6810
NIIN:00-146-7515
MSDS Number: BQQDB
Responsible Party
ST PETERSBURG, FL 33709
US
Emergency Phone: 813-344-1644
Info Phone: 813-344-1644
Cage: 23605
Contractor
Telephone: 813-344-1644
Cage: 23605
Ingredients
SULFURIC ACID (SARA III)
CAS: 7664-93-9
RTECS: WS5600000
Fraction By Weight: 98%
OSHA PEL 1 MG/M3
ACGIH TLV: 1 MG/M3
EPA Report Quantity: 1000 LBS
DOT Report Quantity: 1000 LBS
WATER
CAS: 7732-18-5
RTECS: ZC0110000
Fraction By Weight: 2 - 7%
CONFINED SPACES. RUNOFF TO SEWER
RTECS: 9999999ZZ
SEVERE DMG, OFTEN LEADING TO BLINDESS.
RTECS: 9999999ZZ
RECOVERY MAY BE COMPLETE. EXPOSURE TO THE MIST
RTECS: 9999999ZZ
MAY CAUSE CONJUNCTIVITIS AND LACRIMATION. INGEST
RTECS: 9999999ZZ
FOLLOWED BY VOMITING & DIRRHEA OF DARK, PRECIPITATED
RTECS: 9999999ZZ
PERFORATION OF THE ESOPHAGUS AND STOMACH MAY OCCUR.
RTECS: 9999999ZZ
OCCASNLY LIFTING THE UPPER & LOWER LIDS,
RTECS: 9999999ZZ
APPLY STERILE BANDAGES LOOSELY WITHOUT MEDICATION.
RTECS: 9999999ZZ
QUANTITIES OF WATER IMMEDIATELY TO DILUTE THE ACID.
RTECS: 9999999ZZ
W/SLAKED LIME, SODIUM BICARBONATE/CRUSHED
RTECS: 9999999ZZ
NEUT W/AGRICULTURAL LIME, SLAKED
RTECS: 9999999ZZ
SUITABLE AGENT TO NEUTRALIZE SPILLED MATL TO PH-7.
RTECS: 9999999ZZ
AWAY FROM SPILLED MATL. DO NOT TOUCH SPILLED MATL.
RTECS: 9999999ZZ
IT WITHOUT RISK. USE WATER SPRAY TO REDUCE VAPS. DO
RTECS: 9999999ZZ
THE SUPERVISION OF AN EXPERT. DIKE SPILL FOR LATER
RTECS: 9999999ZZ
KEEP UNNEC PEOPLE AWAY. ISOLATE HAZARD AREA AND
RTECS: 9999999ZZ
Hazards
LD50 LC50 Mixture:LD50: (ORAL,RAT) 2140 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL:CORROSIVE/TOXIC. ACUTE: EXPOSURE
TO CONC CNTNG 5 MG/M3 MAY CAUSE NOSE & THROAT IRRIT, HDCH, COUGH,
AN INCR IN RESP RATE/IMPAIRMENT OF VENT CAPACITY. DELAYED SYMPS MAY
INCL PULM EDEMA, TIGHTNESS IN CHEST, CYANOSIS, HYPOTENSION,
BRONCHITIS OR EMPHYSEMA. CHRONIC: RPTD EXPOS TO MIST CAUSES
CHRONIC(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:TRACHEO-BRONCHITIS, EROSION &
DISCOLORATION OF TEETH, BRONCHIAL PNMEUMONIA OR GI DISTRUBANCES.
SKIN:CORROSIVE. ACUTE:CNTCT MAY CAUSE SEVERE IRRIT & PAIN, BURNS &
VESICULATION. CHRONIC:RPTD/PR LNGD EXPOS TO LIQ/MIST MAY CAUSE
IRRIT & DERM. EYE:CORROSIVE. ACUTE:DIRECT CNTCT W/CONC ACID SOLN
MAY CAUSE (ING 4)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
First Aid
First Aid:INHAL: REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF
RESP). SKIN: REMOVE CONTAM CLTHG & SHOES IMMED. WASH AFFECTED AREA
W/SOAP OR MILD DETERGENT & LRG AMTS OF WATER UNTIL NO EVIDENCE OF
CHEM REMAINS. IN CASE OF BURNS, COVER THE AREA WITH STERILE, DRY
DRESSING. BANDANGE SECURELY, BUT NOT TOO TIGHTLY. GET MED ATTN.
EYES:WASH IMMED W/LRG AMTS OF WATER FOR AT LEAST 15 MIN, (ING 9)
Fire Fighting
Flash Point:NON-FLAMMABLE
Extinguishing Media:DRY CHEM/CARBON DIOXIDE (1984 EMERGENCY RESPONSE
GUIDEBOOK, DOT P 5800.3) LRG FIRES: FLOOD AREA W/WATR FROM A
DISTANCE.
Fire Fighting Procedures:MOVE CNTNRS FROM FIRE AREA IF POSS.COOL
EXPOSED CNTNRS W/H*2O FROM SIDE UNTIL AFTER FIRE IS OUT.WEAR
NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP. (SUPP DATA)
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
Accidental Release
Spill Release Procedures:SOIL SPILL:DIG HOLDING AREA SUCH AS LAGOON,
POND OR PIT FOR CONTAMINANT. DIKE FLOW OF SPILLED MATERIAL USING
SOIL OR SANDBAGS OR FOAMED BARRIERS SUCH AS POLYURETHANE OR
CONCRETE. USE CEMENT POWDER OR FLY ASH TO ABSORB LIQUID MASS. NEUT
SPILL(ING 12)
Neutralizing Agent:SEE SPILL PROCEDURES.
Handling
Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
Exposure Controls
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN . 50 MG/M3: GMOVC, SAF, SCBA, HEPA. 100 MG/M3:
SAF. ESCAPE: GMOVC, SCBA. FIRE FIGHTING: SCBA.
Ventilation:PROVIDE LOCAL EXHAUST VENTILATION SYSTEM TO MEET
PERMISSIBLE EXPOSURE LIMITS.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:CHEM WORK GOGG/FULL LENGTH FSHLD .
Other Protective Equipment:EMPLOYER SHALL PROVIDE AN EYE-WASH FOUNTAIN
WITHIN THE IMMEDIATE WORK AREA FOR EMERGENCY USE.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC:EXTING USING AGENTS INDICATED; DO NOT USE WATER
DIRECTLY ON MATL. IF LRG AMTS OF COMBUST MATLS ARE INVOLVED, USE
WATER SPRAY OR FOG IN FLOODING AMTS. USE WATER SPRAY TO ABSORB
CORROSIV E VAPORS. COOL CNTNRS W/FLOODING AMTS OF WATER FROM AS FAR
A DISTANCE AS POSS. AVOID BRTHG CORR VAPS; KEEP UPWIND.
Chemical Properties
Boiling Pt:B.P. Text:536F,280C
Melt/Freeze Pt:M.P/F.P Text:37.0F,2.8C
Vapor Pres:0.001@ 20C
Vapor Density:3.4
Spec Gravity:1.8
Solubility in Water:SOLUBLE
Appearance and Odor:COLORLESS TO DARK BROWN, OILY LIQUID.
Stability
Stability Indicator/Materials to Avoid:YES
ALCOHOLS & HYDROGEN PEROXIDE, AMMONIUM HYDROXIDE, CHLORATE, METALS
(POWDERED), PERCHLORATES, STEEL.
Stability Condition to Avoid:MAY IGNITE OTHER COMBUST MATLS
(WOOD,PAPER,OIL,ETC). VIOLENT RXN W/H*2O & ORG MATL. FLAMM,POISON
GAS MAY ACCUM IN(ING 3)
Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS INCLUDE
HIGHLY TOXIC FUMES OF SULFUR OXIDES.
Disposal
Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,
STATE AND LOCAL REGULATIONS .
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.